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These included TCA cycle intermediates such as citrate, cis -aconitate, α -ketoglutarate, and various amino acids including glutamate, proline, aspartate, asparagine, and alanine as well as glutathione, pyroglutamate, and ornithine

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The pathway for production of these compounds from DHA under apoplastic conditions involves a mixture of non-enzymatic and enzymatic steps including intermediates such as 4-O-oxalyl L-threonate (Fig